By Irina A. Maretina,Boris I. Ionin
Acetylene platforms current a brand new path to cyclic compounds as a substitute to more conventional equipment hired in classical natural chemistry. The synthesis of cyclic constructions in keeping with acetylene platforms has very important purposes within the formation of nanostructures, clearly taking place compounds and chemosensory fabrics for the layout of nonlinear optics, digital and photonic devices.
Alkynes in Cycloadditions provides a latest overview of regioselective synthesis of fragrant and non-aromatic carbocyclic and heterocyclic ring structures dependent totally on [2+2+2] and [4+2] cycloadditions, and different reactions of acetylenic devices together with enediynes and enyne-allenes.
Topics coated include:
- New suggestions for the formation of fragrant and polynuclear hydrocarbons in response to (Z)-hex-3-en-1,5-diyne and (Z)-hepta-1,2,4-triene-6-yne blocks.
- One-step synthesis of benzene derivatives, β-substituted naphthalenes and acenes by means of the cycloaromatization of enediynes and enyne-allenes through Bergman, Myers-Saito and Shmittel.
- Mechanisms of cycloaromatization leading to the formation of fulvene and indene systems.
- Heterocyclization regarding enyne-carbodiimides.
- New achievements in classical cycloaddition reactions corresponding to the Diels-Alder condensation with acetylenic dienophiles and [2+2] cycloadditions with acetylene components
Alkynes in Cycloadditions offers a complete precis of the literature on tools for the synthesis of ring structures from acetylenes for educational researchers operating within the fields of natural synthesis, actual natural chemistry, organometallic chemistry, catalysis, fabrics technological know-how, nanomaterials and biochemistry.
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